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A Dieckmann condensation involves two ester groups in the exact same molecule and yields a cyclic molecule
This has become thoroughly examined, and in several cases, one can forecast the perception of asymmetric induction, if not the absolute degree of diastereoselectivity. When the enolate includes a stereocenter from the alpha situation, great stereocontrol may very well be understood.
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The aldol response unites two rather straightforward molecules right into a much more advanced one. Enhanced complexity occurs since up to 2 new stereogenic centers (about the α- and β-carbon of the aldol adduct, marked with asterisks inside the plan beneath) are shaped.
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The electrophilic spouse will likely be an aldehyde or ketone (many variants, like the Mannich response, exist). When the nucleophile and electrophile are unique, the reaction known as a crossed aldol response; about the converse, when the nucleophile and electrophile are the exact same, the reaction known as an aldol dimerization.
Hydroxide capabilities like a base and for that reason moves the acidic a-hydrogen generating the reactive enolate ion. This reaction is often observed as an acid-foundation reaction.
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